And when apps request access to your photos, you can share just the images you want-not your entire library,” we know exactly who they have in mind. When Apple says its Photos platform “is designed so that the face recognition and scene and object detection-which power features like For You, Memories, Sharing Suggestions and the People album-happen on device instead of in the cloud. And where Apple’s CSAM issue was linking this on-device ML to external processing, Google’s cloud ML is already external, off-device, a relative black box to users. Apple uses on-device machine learning (ML) to categorize photos, for example, enabling smart searching for objects or people. Behind Apple’s CSAM move was its well-established approach to analyzing your device data. We know that Google applies cloud AI to the photos it stores. “Apple devices are designed to give you control over those memories.” And at the core of this assurance, we have the same device versus cloud debate that framed the CSAM controversy that hit Apple last month. “Your photo and video albums are full of precious moments,” Apple counters to Google’s approach. But limiting Google’s access, also limits its functionality. “For example to surface a trip in our Memories feature or suggest a photo book from a recent trip.”Ĭlearly, you can each take a view as to the personal data you’re comfortable being pulled into Google’s datasets to be mined and analyzed, and Google now offers more controls than ever before to restrict what is shared. “We do use EXIF location data to improve users’ experience in the app,” the company told me. Privacy Labels Apple / Facebook-will also harvest metadata from photos and pull the data into its algorithmically-driven money machine. But the agitated privacy lobby was not assured, especially given Apple’s past challenges in “just saying no” in China, on iCloud storage locations and app censorship, for example. to start and would only expand to countries where those risks could be contained. Political or religious dissent, other crimes, persecuted minorities in parts of the world where Apple sells its devices.Īpple explained in great detail that it had technical protections in place to hamper this, promising it would always say no. Worse-the real issue that holed Apple’s CSAM plans below the waterline was the risk that governments would expand beyond known CSAM content-collated by child safety organizations, to other content. Apple has highlighted the privacy invasion in searching across all your photos in the cloud, that just matching to CSAM databases would be welcome, but does it stop there? And what about the risks inherent in Apple’s technical detail, around false matches and manual reviews? Does that mean our cloud photos on other platforms are regularly flagged and reviewed by desks of manual operators? But turn that around the other way, and there’s an interesting conundrum for the rest of the industry.
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It by no means suggests the real oxidation numbers for the compound(s) ( Karen, 2015). It should be noted that assigning zero oxidation numbers is solely for the balancing purpose. Since a redox reaction requires the same amount of gain/loss of electrons, we first find out the increase/decrease of the oxidation numbers, which represents the number of loss/gain of electrons then we use common multiple to balance the equation with minimum integral coefficients. ↑ denotes the sum of increase of oxidation numbers and ↓ denotes the sum of decrease of oxidation numbers. We use exhaustive oxidation of glucose (C 6H 12O 6) by KMnO 4 in acidic conditions ( Guo, 1997) to illustrate this balancing process. When encountering a compound that is hard to assign oxidation number for all atoms in it, we can assign zero oxidation number for them in such redox-active compound in one side (reactant side or product side) of a reaction, in case it is easy to assign oxidation numbers for the molecules in the other side. As a special case of Ludwig’s unconventional oxidation number method ( Ludwig, 1996), a strategy using zero oxidation number to balance some redox equations is presented herein. It could be challenging for balancing organic reactions such as exhaustive oxidations of organic compounds because it might involve different oxidation numbers for same type of atoms or a fractional oxidation number on average. Chemistry Teacher International, 3(3), 313–323.For high school students and first year undergraduate students, balancing oxidation-reduction (redox) equations is a good training for understanding gain/loss of electrons and half-reaction in electrochemistry ( Andraos, 2016 Herndon, 1997 Jensen, 2009). Application of stoichiometric hydrogen atoms for balancing organic combustion reactions. Journal of Chemical Education, 74(7), 744. Physical Chemistry Chemical Physics, 16, 7647–7661. The concept, reality and utility of single-site heterogeneous catalysts (SSHCs). The relative explosive power of some explosives. Journal of Chemical Education, 72(12), 112. Redox challenges: Good times for puzzle fanatics. Journal of Chemical Education, 73(6), 507. Journal of Chemical & Engineering Data, 61(1), 207–212. A low sensitivity energetic salt based on Furazan derivative and melamine: Synthesis, structure, density functional theory calculation, and physicochemical property. Journal of Chemical Education, 58(8), 642. Balancing complex redox equations by inspection. Journal of Chemical Education, 56(3), 181. Journal of Heterocyclic Chemistry, 33, 569–574. A classification of organic redox reactions and writing balanced equations for them, with special attention to heteroatoms and heterocyclic compound. Journal of Chemical Education, 59(6), 523. Balancing chemical equations with a calculator. Oxidation state, a long-standing issue! Angewandte Chemie International Edition, 2015(54), 4716–4726. On balancing chemical equations: Past and present. A new inspection method for balancing redox equations. Journal of Chemical Education, 72(8), 716. Giomini, C., Marrosu, C., & Cardinali, M. Journal of Chemical Education, 36(2), 77. Oxidation of M4Si4 (M = Na, K) to clathrates by HCl or H2O, Journal of the American Chemical Society, 129(17), 5348–5349.īurrell, H. Journal of Chemical Education, 93(7), 1330–1334.īohme, B., Guloy, A., Tang, Z., Schnelle, W., Burkhardt, U., Baitinger, M., & Grin, Y. Using balancing chemical equations as a key starting point to create green chemistry exercises based on inorganic syntheses examples. |
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